Syntheses and Spectral Properties of 2,6-Disubstituted-trans-decalins

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概要

• 論文の詳細を見る

• Various stereoisomers of 6-substituted-trans-2-decalols have been synthesized ; four possible epimers for 6-methoxy and 6-chloro derivatives, three epimers for 6-cyano derivatives, and two epimers for 6-phenyl, 6-carbomethoxy, and 6-oxo derivatives were reported. The structures of these compounds were assigned by proton magnetic resonance and infrared spectroscopies. A paramagnetic shift reagent, tris (dipivalomethanato) europium (III), was successfully applied in the proton magnetic resonance spectra of the two epimers of trans-2-decalol to establish their structures. The spectral data obtained were also presented and discussed.

• 社団法人日本薬学会の論文
• 1972-02-25

著者

• 武田 健一

  Shionogi Research Laboratory Shionogi & Co. Ltd.

• 山本 貞雄

  Shionogi Research Laboratory, Shionogi & Co., Ltd.

• 武田 健一

  塩野義製薬(株)

• 武田 健一

  塩野義製薬株式会社研究所

• 武田 健一

  Research Laboratory Shionogi & Co. Ltd.

• 武田 健一

  塩野義研

• Takeda Ken'ichi

  Shionogi Research Laboratory Shionogi & Co. Ltd.

• 山本 貞雄

  Shionogi Research Laboratory Shionogi And Co. Ltd.

• 武田 健一

  Shionogi Research Laboratories

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