Chiral Discrimination in Electrocatalytic Oxidation of (R)- and (S)-1-Phenylethanol Usinga Chiral Nitroxyl Radical as Catalyst
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概要
- 論文の詳細を見る
A chiral nitroxyl radical, (6R, 7S, 10R)-4-oxo-2,2,7-trimethyl-10-isopropyl-1-azaspiro[5.5]undecane-N-oxyl, was used as catalyst in the electrooxidation reaction of (R)- and (S)-1-phenyl-ethanol. Cyclic voltammetric studies showed that the catalytic current for the oxidation of (R)-1-phenylethanol is highly enhanced as compared with a very small enhancement in the oxidation current for the (S)-isomer. The (R)-isomer can be detected selectively in a mixture of (R)- and (S)-1-phenylethanol, even in the presence of an excess amount of (S)-isomer.
- 公益社団法人日本薬学会の論文
- 1999-07-15
著者
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安斉 順一
東北大学大学院薬学研究科
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Kobayashi Y
Graduate School Of Pharmaceutical Sciences Tohoku University
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Anzai Jun-ichi
Graduate School Of Pharmaceutical Sciences Tohoku University
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KASHIWAGI Yoshitomo
Graduate School of Pharmaceutical Sciences, Tohoku University
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柏木 良友
Graduate School Of Pharmaceutical Sciences Tohoku University
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UCHIYAMA Kazumi
Graduate School of Pharmaceutical Sciences, Tohoku University
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KURASHIMA Futoshi
Graduate School of Pharmaceutical Sciences, Tohoku University
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KIKUCHI Chikara
Graduate School of Pharmaceutical Sciences, Tohoku University
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Kurashima F
Niigata Coll. Pharmacy Niigata
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Uchiyama K
Graduate School Of Pharmaceutical Sciences Tohoku University
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Kashiwagi Yoshitomo
Phamaceutical Institute Tohoku University
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