Solvent Effect on Photoisomerisation of 3-Methyl-1-phenylbutane-1,2-dione 2-Oxime
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概要
- 論文の詳細を見る
Photoisomerisation of (2E)- and (2Z)-3-methyl-1-phenylbutane-1,2-dione 2-oxime (MPBDO) in several solvents was studied. With increasing dielectric constants of solvents, kinetic constants of forward reactions (E-form→Z-form) did not change appreciably but those of reverse reactions (Z-form→E-form) decreased. The positive correlation was found between equilibrium constants of photoisomerisation and dielectric constants of solvents.
- 公益社団法人日本薬学会の論文
- 2002-07-01
著者
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池田 衡
丸石製薬株式会社中央研究所
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後藤 義久
Faculty of Pharmaceutical Sciences Kanazawa University
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Niiya T
Faculty Of Pharmaceutical Sciences Fukuoka University
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Yukawa M
Fukuoka Univ. Fukuoka Jpn
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Yukawa Miho
Faculty Of Pharmaceutical Sciences Fukuoka University
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Goto Yoshinobu
Faculty Of Pharmaceutical Sciences Fukuoka University
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Goto Yoshinobu
Department Of Clinical Neurophysiology Graduate School Of Medical Sciences Neurological Institute Fa
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Niiya Tokihiro
Faculty Of Pharmaceutical Sciences Fukuoka University
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IKEDA Hirohito
Faculty of Pharmaceutical Sciences, Fukuoka University
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SUZUE Takuya
Faculty of Pharmaceutical Sciences, Fukuoka University
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Suzue Takuya
Faculty Of Pharmaceutical Sciences Fukuoka University
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Ikeda Hirohito
Faculty Of Pharmaceutical Sciences Fukuoka University
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Yukawa Miho
Faculty Of Pharmaceutical Fukuoka University
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Ikeda Hirohito
Faculty Of Pharmaceutical Fukuoka University
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