Mechanism of Conversion of Secondary Amines to Primary Amines by Sodium Hypochlorite (生体成分の高速液体クロマトグラフィ-)
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概要
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The mechanism of the conversion of secondary amines by sodium hypochlorite (NaOCl) to compounds that form fluorescent adducts with o-phthalaldehyde (OPA)/2-mercaptoethanol (ME) was investigated by analyzing the reaction mixtures of secondary amines and NaOCl by high performance liquid chromatography (HPLC) and high performance thin-layer chromatography (HPTLC). Methylamine was found to be produced from N-methylamino acids, L-epinephrine, DL-metanephrine and N-methylcyclohexylamine. While N-phenylbenzylamine and N-alkylbenzylamines gave aniline and the corresponding alkylamines, respectively, N-alkylanilines produced the corresponding alkylamines rather than aniline. α-Amino acids were converted to ammonia by NaOCl. On the basis of these findings, mechanism of the conversion of secondary amines to primary amines by NaOCl were proposed.
- 社団法人日本分析化学会の論文
- 1984-07-05
著者
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Tamura Zenzo
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences The University Of Tokyo
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Tamura Zenzo
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences University Of Tokyo:(present A
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NAKAMURA^[○!R] Hiroshi
Department of Analytical Chemistry, Faculty of Pharmaceutical Sciences, University of Tokyo
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HIMURO Akira
Department of Analytical Chemistry, Faculty of Pharmaceutical Sciences, University of Tokyo
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Himuro Akira
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences University Of Tokyo:(present A
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Nakamura Hiroshi
Department Of Analytical Chemistry Faculty Of Pharmaceutical Sciences Science University Of Tokyo
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Nakamura Hiroshi
Department of Analytical Chemistry, Faculty of Pharmaceutical Sciences, University of Tokyo
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