Mechanistic Studies of Octahydrophenazine Formation from a 2-Hydroxycyclohexanone/Ammonium Acetate Model System in Ethanol

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概要

• 論文の詳細を見る

• Synopsis Model systems composed of 2-hydroxycyclohexanone and ammonium acetate in a mole ratio of 1 to 3 were set up to study the formation of octahydrophenazine (OHP). Octahydrophenazine and an intermediate were isolated and characterized by GC/MS (EI and CI). This intermediate was the condensation pfoduct between a molecule of 2-hydroxycyclohexanone and 2-amino-cyclohexanone via the Schiff base formation mechanism. A larger amount of the intermediate than of OHP was found in the solvent system containing less than 20% ethanol, the relative proportion of the intermediate decreasing as the percentage of ethanol was increased. The formation mechanism for OHP is proposed.

• 社団法人日本農芸化学会の論文
• 1996-03-23

著者

• Fu Hui-yin

  Department Of Food Science Rutgers University

• Huang T‐c

  National Pingtung Polytechnic Inst. Pingtung Twn

• Huang Tzou-chi

  Department Of Food Science And Technology National Pingtung Polytechnic Institute

• HO Chi-Tang

  Department of Food Science, Rutgers University

• Ho Chi-tang

  Department Of Food Science Cook College New Jersey Agricultural Experiment Station Rutgers Universit

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