δ-鉄の酸素溶解度におよぼす第三元素の影響

概要

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Non metallic inclusions change their composition in solid iron during annealing at high temperatures. Therefore, it is desirable to know the effects of the alloying elements on the oxygen in solid iron. This experiment was carried out to know the effect of the alloying elements on the solubility of the oxygen and to determine the interaction coefficients of oxygen in δ-iron. The crucible assembly was lowered very slowly under purified argon gas in Tamman furnace and the equilibrium between solid iron and liquid was observed. The relation of the distribution ratio of oxygen in Fe-O system (Lo') and in Fe-O-X system (Lo) is log Lo=log Lo'+log f^<(X)>_I/f^<(X)>_S where f^<(X)>_S and f^<(X)>_I are the interaction coefficients in solid and liquid iron respectively. By using the relation, we can get the interaction coefficients in solid iron. These results are as follows : log f^<(Mn)>_S=-1.83 [% Mn] <0.15% log f^<(Cr)>_S=-0.23 [% Cr] <0.5% log f^<(Si)>_S=-12.14 [% Si] <0.1% log f^<(V)>_S=-1.71 [% V] <0.3% log f^<(Ni)>_S=-0.105 [% Ni] <1.0%
社団法人日本鉄鋼協会の論文
1969-11-01