Paramagnetic Resonance Spectra of Some Cupric Salts (I)
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概要
- 論文の詳細を見る
The paramagnetic resonance spectra of some ammine, ethylenediammine, and pyridine derivatives of hydrated cupric salts were examined, using their single crystals and microwaves of λ=32〜5 mm. In the cases of [Cu(NH_3)_4] SO_4・H_2O and [Cu(en)_2] Cl_2・χH_2O, detailed analysis of spectra was performed usjng the structural data from x-ray analysis given by Mazzi. In the other cases, analysis was discussed under an assumption of inequivalent magnetic units. Results thus obtained are fully explained by the treatments given by Abragam and Pryce with modified λ, the spin-orbit coupling coefficient, so the forces acting between the central copper ion and the surrounding nitrogen atmos are supposed to be mainly ionic rather than covalent, as in the cases of usual hydrates. Exchange energies between copper ions are also discussed.
- 社団法人日本物理学会の論文
- 1956-09-05
著者
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Abe Hidetaro
Institute For Solid State Physics The University Of Tokyo Of Tokyo
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Abe Hidetaro
Institute Of Science And Technology University Of Tokyo
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Ono Kazuo
Institute For Solid State Physics The University Of Tokyo
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Ono Kazuo
Institute Of Science And Technology University Of Tokyo
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Abe Hidetaro
Institute For Solid State Physics The University Of Tokyo
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ABE Hidetaro
Institute of Science and Technology, University of Tokyo
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