Non-additive Intermolecular Potential in Gases : II. Cluster Integrals
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概要
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The van der Waals interaction discussed in Part I are applied to the equation of state of rare gases. The potential energy between three identical atoms is assumed to be [numerical formula] Here γ_<ij> is the distance between i th and j th atoms, θ_i's are inner angles of the triangle formed by the three atoms, and [numerical formula] Use is made of a relation proved in Part I, 4ν=3_<αμ>, in which α is the polarizability. For this model of the intermolecular potential we have calculated the third cluster integral including quantum effect. By virtue of the non-additive part of the intermolecular potential agreement between observed and calculated values is very good.
- 社団法人日本物理学会の論文
- 1956-10-05
著者
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Kaneko Shobu
Department Of Applied Physics Faculty Of Engineering The University Of Tokyo
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Kihara Taro
Department Of Physics Faculity Of Science University Of Tokyo
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KOBA Saburo
Department of Physics, Faculty of Science, University of Tokyo
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Koba Saburo
Department Of Physics Faculty Of Science University Of Tokyo
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Koba Saburo
Department Of Physics Faculty Of Scicnce University Of Tokyo
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