燒結法により作成したMg2Ni電極の充放電特性に及ぼす酸化の影響

概要

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The influence of pre-oxidation on charge/discharge characteristics of sintered Mg2Ni electrodes was examined with an open electrochemical cell. Mg2Ni powder was first oxidized slightly in air at 473 K for 5-360 min and then sintered in argon atmosphere at 823 K. The cyclic stability of discharge capacity was improved markedly by pre-oxidation. Maximum cycle life was obtained using 20 min pre-oxidation. The mechanism by which pre-oxidation influences cyclic stability was examined via density measurement and surface analysis. The sintering rate had a maximum value for 20 min pre-oxidation. An MgO layer was formed on the surface of Mg2Ni during sintering and growth rate of the MgO layer decreased with pre-oxidation. Improvement of cyclic stability with pre-oxidation was attributed to the firm aggregation between Mg2Ni powder particles due to reduction in the thickness of MgO layer.
富山大学の論文