In situ Activating Glycosylation of 6-Deoxysugars: Synthesis of O-α-_D-Fucosyl-(1→4)-O-α-_D-fucosyl-(1→4)-O-α-_D-quinovosyl-(1→4)-_D-quinovose

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概要

• 論文の詳細を見る
• Chemical Society of Japanの論文
• 2000-04-15

著者

• KOTO Shinkiti

  School of Pharmaceutical Sciences, Kitasato University

• Koto Shinkiti

  School Of Pharmaceutical Sciences Kitasato University

• Hirooka Motoko

  School Of Pharmaceutical Sciences Kitasato University

• Kusunoki Ami

  School Of Pharmaceutical Sciences Kitasato University

関連論文

• Benzyl Derivatives of N-2,4-Dinitrophenyl-D-glucosamine and Their Use for Oligosaccharide Synthesis
• Syntheses of Penta-O-benzyl-myo-inositols, O-β-L-Arabinosyl-(1→2)-sn-myo-inositol, O-α-D-Galactosyl-(1→3)-sn-myo-inositol, and O-α-D-Galactosyl-(1→6)-O-α-D-Galactosyl-(1→3)-sn-myo-inositol
• Glycosylation Using 2-Azido-3,4,6-tri-ο-benzyl-2-deoxy-D-glucose,-galactose, and -mannose with the Aid of ρ-Nitrobenzenesulfonyl Chloride-Silver Trifluoromethanesulfonate-Triethylamine System
• Synthesis of Glucose-Containing Linear Oligosaccharides Having α(1→4) and α(1→6) Linkages Using Stereoselective Dehydrative Glycosylation
• Synthesis of a 2-Acetamido-2-deoxy-β-D-mannuronic Acid-Containing Artificial Glycolipid Corresponding to the Repeating Unit of Teichuronic Acid from Micrococcus luteus
• Synthesis of β-D-Ribofuranosyl-(1→3)-α-L-rhamnopyranosyl-(1→3)-L-rhamnopyranose by in situ Activating Glycosylation Using 1-OH Sugar Derivative and Me_3SiBr-CoBr_2-Bu_4NBr-Molecular Sieves 4A System
• Glycosylation Using Hemiacetal Sugar Derivatives : Synthesis of O-α-D-Rhamnosyl-(1→3)-O-α-D-rhamnosyl-(1→2)-D-rhamnose and O-α-D-Tyvelosyl-(1→3)-O-α-D-mannosyl-(1→4)-L-rhamnose
• Syntheses of O-β-D-Mannosyl-(1→4)-O-α-D-mannosyl-(1→3)-L-rhamnose and O-(2-Acetamido-2-deoxy-β-D-mannosyl)-(1→4)-O-α-D-galactosyl-(1→4)-D-galactose via In-situ-activating Glycosylation Using 2-O-Acetyl-3, 4, 6-tri-O-benzyl-D-glucose
• Stereoselective Syntheses of α-Glucuronides Using Dehydrative Glycosylation
• Synthesis of Methyl O -IX- D Mannosyl (1→4)-[(3-O-methyl-α-D-mannosyl)-(1→4) ]_n 3-O methyl-α-D-mannosides (n=O, 1, and 2) via Dehydrative Glycosylation
• Dehydrative Glycosylation by Diethylaminosulfur Trifluoride (DAST)-Tin(II) Trifluoromethanesulfonate-Tetrabutylammonium Perchlorate-Triethylamine System
• In situ Activating Glycosylation of 6-Deoxysugars: Synthesis of O-α-_D-Fucosyl-(1→4)-O-α-_D-fucosyl-(1→4)-O-α-_D-quinovosyl-(1→4)-_D-quinovose
• Syntheses of Isomaltose, Isomaltotetraose, and Isomaltooctaose
• A study of the rapid anomerization of poly-O-benzyl-.BETA.-D-glucopyranosides with titanium tetrachloride.
• A stereoselective one-stage .ALPHA.-glucosylation with 2,3,4,6-tetra-O-benzyl-.ALPHA.-D-glucopyranose and a mixture of methanesulfonic acid, cobalt(II) bromide, and tetraethylammonium perchlorate.
• The direct synthesis of methyl 2,4-di-O-benzyl-.ALPHA.-D-xylopyranoside by the regiospecific benzylation of methyl .ALPHA.-D-xylopyranoside.
• Synthesis of O-.BETA.-D-glucopyranosyl-(1.RAR.2)-O-.BETA.-D-glucopyranosyl-(1.RAR.6)-D-glucopyranose; Dehydrative .BETA.-D-glucosylation using 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucopyranose.
• The synthesis of .ALPHA.-D-galactopyranosyl and .ALPHA.-D-mannopyranosyl 2-amino-2-deoxy-.ALPHA.-D-glucopyranosides and the conformation of their glycoside linkage.
• .ALPHA.-D-glucosylation by 6-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose using trimethylsilyl triflate and pyridine. Synthesis of .ALPHA.-maltosyl and .ALPHA.-isomaltosyl .ALPHA.-D-glucosides.
• Partial benzylation of methyl .ALPHA.- and .BETA.-D-galactopyranosides.
• Stereoselective synthesis of mixed acetal glycosides by reaction of tri-O-acetyl-N-(2,4-dinitrophenyl)-.ALPHA.-D-glucosaminyl bromide with alcohol in acetone.
• A through-process for the preparation of methyl per-O-acetyl 1-thio-glycosides from aldoses.
• Synthesis of Anomeric Methyl 6-O-(L-Mycarosyl)-β-D-glucosaminides and 4-O-(L-Mycarosyl)-β-D-mycaminosides
• The Synthesis of Methyl 2,4,6-Tri-O-benzyl-α-D-glucopyranoside
• Partially benzylated derivatives of 6-deoxy-D-glucose.
• .ALPHA.-Glucosylation of phenols with tetra-O-benzyl-.ALPHA.-D-glucose.
• The stereoselective dehydrative .ALPHA.-glucosylation using 6-O-acetyl- and 6-O-p-nitrobenzoyl-2,3,4-tri-O-benzyl-D-glucopyranoses.
• Glucosidation of tetra-O-benzyl-.ALPHA.-D-glucose with chlorosilane and silver sulfonate.
• Preparation of 2,3,4,6-tetra-O-benzyl-D-mannose.
• The Synthesis of Purine Nucleosides of L-Mycarose and L-Cladinose
• Stereoselective .ALPHA.-glucosylation with tetra-O-benzyl-.ALPHA.-D-glucose and a mixture of trimethylsilyl bromide, cobalt(II) bromide, tetrabutylammonium bromide, and a molecular sieve. A synthesis of 3,6-di-O-(.ALPHA.-D-glucopyranosyl)-D-glucose.
• The Synthesis of 3-Amino-3-deoxy-D-allose and Related Substances
• 2-methoxyethyl group for protection of reducing hydroxyl group of aldose.
• The glucosylation of several alcohols with tetra-O-benzyl-.ALPHA.-D-glucopyranose and a mixture of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine.

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