Simultaneous Measurement of Electron and Ion Transfer in All-Solid Ion-Transfer Device Made of Transition Metal Cyanide Films
スポンサーリンク
概要
- 論文の詳細を見る
Simultaneous measurements of electron and ion transfers were performed in an all solid ion-transfer device made of transition metal cyanide films, indium--tin oxide (ITO)/NaxNi[Fe(CN)6]0.68\Cdot5.1H2O (NNF68)/NaxCo[Fe(CN)6]0.90\Cdot2.9H2O (NCF90)/ITO, against time (t) and temperature (T). At 330 K, the current density (I) steeply decreases below 10 s, and then becomes nearly constant above 10 s. We found that there exists time-lag between the electron and ion transfers. We analyzed the I--t curves with an equivalent circuit, which consists of the external component (R_{\text{ex}}) of resistance, the bulk component (R') resistance, the leak current component (R_{\text{leak}}), and the capacitance (C). The large R' component was ascribed to suppressed current density owning to the local charge neutrality.
- 2011-12-25
著者
-
Moritomo Yutaka
Graduate School Of Pure And Applied Science University Of Tsukuba
-
Shibata Takayuki
Graduate School Of Engineering Hokkaido University
-
Kamioka Hayato
Graduate School Of Pure And Applied Science University Of Tsukuba
-
Shibata Takayuki
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
-
Moritomo Yutaka
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan
関連論文
- Isotope Effect on the Infrared Photoluminescence Decay of Interstitial Oxygen Molecules in Amorphous SiO_2
- Thin Film Electrode of Prussian Blue Analogue for Li-ion Battery
- Oxidization Process of Fe--Ni Mixed Prussian Blue Analogue Investigated by Valence-Differential Spectroscopy
- Size Dependent Cation Channel in Nanoporous Prussian Blue Lattice
- Doping-Induced Structural Phase Transition in Na_Co[Fe(CN)_6]_2.9H_2O
- Effect of Mixing Modes in Chemiluminescent Detection of Epinephrine with Lucigenin by an FIA System Fabricated on a Microchip
- Quick Response of All Solid Electrochromic Device
- Cubic-Rhombohedral Structural Phase Transition in Na1.32Mn[Fe(CN)6]0.83\Cdot3.6H2O
- High-Pressure Raman Spectroscopy of Transition Metal Cyanides
- Lattice-Mediated Propagation of Photoinduced Phase Transition in Co--Fe Cyanide
- Oxidization/Reduction Process of Prussian Blue Film as Investigated by Valence-Differential Spectroscopy
- Crystallization Process of Photoexcited High-Spin Sites in Co--Fe Cyanide Film
- Thermal Rectification in the Vicinity of a Structural Phase Transition
- Charge-Transfer State and Charge Dynamics in Poly(9,9'-dioctylfluorene-co-bithiophene) and [6,6]-Phenyl C_-butyric Acid Methyl Ester Blend Film
- Thin Film Electrodes of Prussian Blue Analogues with Rapid Li^+ Intercalation
- Interface Dependence of Charge Formation Dynamics in Hexabenzocoronene-C_
- Structural Phase Diagram of Mn--Fe Cyanide against Cation Concentration
- Cation Extraction Process in Bilayer Cyanide Film as Investigated by Depth-Resolved X-ray Absorption Spectroscopy
- Fast Carrier Formation from Acceptor Exciton in Low-Gap Organic Photovotalic
- Structural Properties of Manganese Hexacyanoferrates against Li Concentration
- Simultaneous Measurement of Electron and Ion Transfer in All-Solid Ion-Transfer Device Made of Transition Metal Cyanide Films
- Doping-Induced Structural Phase Transition in Na1.6-xCo[Fe(CN)6]0.902.9H2O
- Electronic Structure of Hole-Doped Transition Metal Cyanides
- Structural, Electronic, and Electrochemical Properties of Li
- Structural Response of P2-Type Na
- Fabrication of Epitaxial Interface between Transition Metal Cyanides
- Electronic State of P2-Type Na
- Pressure-Induced Phase Transition in Zn–Fe Prussian Blue Lattice
- Electronic State of P2-Type Na[x]MO₂ (M = Mn and Co) as Investigated by In situ X-ray Absorption Spectroscopy
- Cobalt Hexacyanoferrate as Cathode Material for Na^+ Secondary Battery
- Molecular mixing in donor and acceptor domains as investigated by scanning transmission X-ray microscopy