Oxidization Process of Fe--Ni Mixed Prussian Blue Analogue Investigated by Valence-Differential Spectroscopy
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概要
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The oxidization process of the Fe--Ni mixed Prussian blue analogue (Fe0.2Ni0.8)[Fe(CN)6]0.67$\Cdot$$z$H2O was investigated by means of valence-differential spectroscopy. The spectroscopy revealed that the oxidization process selectively starts from the intermediate clusters. With a further increase in the oxidization level, all intermediate clusters are oxidized, and then Fe-rich clusters begin to be oxidized. On the basis of these results, we will discuss the redox process of the Ni--Fe cyano mixed crystal.
- 2011-03-25
著者
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Kurihara Masato
Department Of Cardiology Tokyo Medical College Kasumigaura Hospital
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Moritomo Yutaka
Graduate School Of Pure And Applied Science University Of Tsukuba
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Ishizaki Manabu
Department Of Material And Biological Chemistry Faculty Of Science Yamagata University
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Omura Ayako
Graduate School Of Pure And Applied Science University Of Tsukuba
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Kurihara Yutaro
Graduate School Of Pure And Applied Sciences University Of Tsukuba
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Ishizaki Manabu
Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Yamagata 990-8560, Japan
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Moritomo Yutaka
Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
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Kurihara Masato
Department of Material and Biological Chemistry, Faculty of Science, Yamagata University, Yamagata 990-8560, Japan
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