Visible Light-Induced Catalytic Oxidation Using Zeolite Encapsulating Two Distinct Metal Complexes
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概要
- 論文の詳細を見る
Y-type zeolite encapsulating two distinct metal complexes has been synthesized. This zeolite contains Ru(bpy)3 (bpy = 2,2$'$-bipyridine) and Mn(saloph) [saloph = N,N$\ake'$-bis(salicylidene)-o-phenylenediamine] as photoinducing and oxidative catalytic sites, respectively. The zeolite showed the quenching of the emission, resulting in the effective electron/energy transfer from the Ru\text{II center to the Mn\text{II center in it. The oxidation reaction of dimethyl sulfide with the zeolite has been accelerated by photoirradiation. This phenomenon indicates that the electron/energy transfer from Ru(bpy)3 units affects the oxidation reaction on Mn(saloph) units.
- 2011-01-25
著者
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Ozawa Tomohiro
Department Of Applied Chemistry Faculty Of Engineering Nagoya Institute Of Technology
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INOMATA Tomohiko
Department of Applied Chemistry, Nagoya Institute of Technology
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Funahashi Yasuhiro
Department Of Applied Chemistry Graduate School Of Engineering Nagoya Institute Of Technology
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Masuda Hideki
Department Of Applied Chemistry Faculty Of Engineering Nagoya Institute Of Technology
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Funahashi Yasuhiro
Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
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Nagai Yoshimasa
Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
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Ohata Nayumi
Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
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Ozawa Tomohiro
Department of Material Science and Engineering, Graduate School of Engineering, Nagoya Institute of Technology, Nagoya 466-8555, Japan
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