Effect of Humidity on Transport Mechanism in Ag/7,7,8,8-Tetracyanoquinodimethane Bilayer Films
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概要
- 論文の詳細を見る
Ag/7,7,8,8-tetracyanoquinodimethane (TCNQ) bilayer films were prepared on glass substrates by alternate vacuum deposition of Ag and TCNQ. The metal–organic complex Ag–TCNQ was formed via transport of Ag+ in the film at a temperature of 25 °C and in atmosphere with different humidities. The transport behavior of Ag+ in the organic layer in dry and wet atmospheres was studied by measurement of optical transmittance spectra. An accelerated transport phenomenon has been observed with the increase in the relative humidity. The results showed that the transport time and relative humidity follow an inverse law. It has been found that the transport mechanism was changed from solid-state diffusion in dry atmosphere to electrochemical diffusion in wet atmospheres. A transport model based on water absorption and condensation was established to explain the effect of humidity on the transport process in the films.
- Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
- 2006-04-15
著者
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Wu Weiwei
Department Of Cardiovascular Surgery Norman Bethune Medical University
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Li Jin
Department Of Medical Oncology Cancer Hospital Fudan University
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Liu Ping
Department Of Applied Chemistry Faculty Of Engineering Okayama University
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Wu Weiwei
Department of Materials Science, Fudan University, 220 Handan road, Shanghai, 200433, P. R. China
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Zhong Cheng
Department of Materials Science, Fudan University, 220 Handan road, Shanghai, 200433, P. R. China
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Jiang Yiming
Department of Materials Science, Fudan University, 220 Handan road, Shanghai, 200433, P. R. China
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Guo Feng
Department of Materials Science, Fudan University, 220 Handan road, Shanghai, 200433, P. R. China
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Liao Jiaxing
Department of Materials Science, Fudan University, 220 Handan road, Shanghai, 200433, P. R. China
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Li Jin
Department of Materials Science, Fudan University, 220 Handan road, Shanghai, 200433, P. R. China
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