Synthesis and Properties of 1-Methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridinium $ p$-Toluenesulfonate Derivatives with Isomorphous Crystal Structure

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概要

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• DAST, 1-methyl-4-{2-[4-(dimethylamino)phenyl]ethenyl}pyridinium $ p$-toluenesulfonate, has been recently reported as an efficient THz-wave generator by difference frequency generation. In this study, two DAST derivatives, i.e., perdeuterated DAST (DAST-$d_{26}$) and DASC with $ p$-chlorobenzenesulfonate replacing the $ p$-toluenesulfonate of DAST, were investigated as model compounds to analyze the THz-wave intensity variation of DAST as a function of frequency. X-ray crystallographic analyses of DAST-$d_{26}$ and DASC were carried out for the first time, and it was found that both compounds gave crystals isomorphous with DAST. Their basic properties were also investigated.

• Published by the Japan Society of Applied Physics through the Institute of Pure and Applied Physicsの論文
• 2005-07-15

著者

• Nakanishi Hachiro

  Institute For Chemical Reaction Science Tohoku University

• Taniuchi Tetsuo

  Institute Of Multidisciplinary Research For Advanced Materials Tohoku University

• Okada Shuji

  Department Of Pathology Ageo Medical Laboratory

• Mineno Yoshihiro

  Institute Of Multidisciplinary Research For Advanced Materials Tohoku University

• Glavcheva Zornitza

  Institute Of Multidisciplinary Research For Advanced Materials Tohoku University

• Odani Toru

  Institute Of Multidisciplinary Research For Advanced Materials Tohoku University

• Umezawa Hirohito

  Institute Of Multidisciplinary Research For Advanced Materials Tohoku University

• Ikeda Satoshi

  Institute Of Multidisciplinary Research For Advanced Materials Tohoku University

• Nakanishi Hachiro

  Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

• Okada Shuji

  Department of Polymer Science and Engineering, Faculty of Engineering, Yamagata University, 4-3-16 Jonan, Yonezawa, Yamagata 992-8510, Japan

• Umezawa Hirohito

  Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

• Odani Toru

  Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 980-8577, Japan

• TANIUCHI Tetsuo

  Institute for Materials Research, Tohoku University

• Okada Shuji

  Department of Chemistry, School of Science and Engineering, Waseda University

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