Growth of GaN Directly on Si(111) Substrate by Controlling Atomic Configuration of Si Surface by Metalorganic Vapor Phase Epitaxy
スポンサーリンク
概要
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The direct growth of a GaN epitaxial layer on a Si(111) substrate by metalorganic vapor phase epitaxy (MOVPE) was performed using a low-temperature (LT)-GaN buffer layer with no Al-containing intermediate layer (e.g., AlN or AlGaN). No deterioration in the Si surface caused by the reaction between Si and Ga vapor was observed. However, when there were Ga droplets on the surface, Ga and Si formed a Ga–Si alloy, which caused the generation of numerous holes on the surface by melt-back etching at high temperatures. In addition, it was revealed that the coverage of the LT-GaN buffer layer on Si was strongly affected by the hydrogen (H2) partial pressure in the carrier gas. Using nitrogen (N2) carrier gas, a complete coverage of the LT-GaN buffer layer could be achieved directly over the Si surface. These features can be explained by the facts that the Si surface is partially terminated by hydrogen atoms and the coverage of hydrogen on Si surface depends on H2 partial pressure.
- 2006-05-25
著者
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Matsuo Yuriko
Division Of Fundamental Mechanics Research Institute For Applied Mechanics Kyushu University
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TAKEMOTO Kikurou
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and
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MURAKAMI Hisashi
Strategic Research Initiative for Future Nano-Science and Technology, Institute of Symbiotic Science
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IWAMOTO Tomoyuki
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and
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KANGAWA Yoshihiro
Division of Fundamental Mechanics, Research Institute for Applied Mechanics, Kyushu University
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KUMAGAI Yoshinao
Strategic Research Initiative for Future Nano-Science and Technology, Institute of Symbiotic Science
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KOUKITU Akinori
Strategic Research Initiative for Future Nano-Science and Technology, Institute of Symbiotic Science
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Matsuo Yuriko
Division of Fundamental Mechanics, Research Institute for Applied Mechanics, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan
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Koukitu Akinori
Strategic Research Initiative for Future Nano-Science and Technology, Institute of Symbiotic Science and Technology, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan
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Kangawa Yoshihiro
Division of Fundamental Mechanics, Research Institute for Applied Mechanics, Kyushu University, 6-1 Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan
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Iwamoto Tomoyuki
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan
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