Sugar-sensitive supramolecular structures based on phenylboronic acid-modified cyclodextrins
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概要
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Supramolecular structures were developed from phenylboronic acid-modified cyclodextrins (PBA-CyDs). The intermolecular interaction between the PBA moiety and the CyD cavity was proved using 2D NMR and powder X-ray diffraction techniques. PBA-α-CyD formed a head-to-tail supramolecular polymer, whereas PBA-β-CyD formed a head-to-head dimer. The supramolecular structures were disintegrated in the presence of sugars owing to the resulting boronate sugar interactions.
著者
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Seki Toshinobu
Faculty Of Pharmaceutical Sciences Josai University
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Egawa Yuya
Faculty of Pharmaceutical Sciences, Josai University
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YAMANOI Takashi
The Noguchi Institute
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Egawa Yuya
Faculty Of Pharmaceutical Sciences Josai University
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ODA Yoshiki
The Noguchi Institute
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Miki Ryotaro
Faculty Of Pharmaceutical Sciences Josai University
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Seki Tomohiro
Faculty of Pharmaceutical Sciences, Josai University
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Nakamura Kiminobu
Faculty of Pharmaceutical Sciences, Josai University
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三木 涼太郎
Faculty of Pharmaceutical Sciences, Josai University
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小田 慶喜
The Noguchi Institute
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山ノ井 孝
The Noguchi Institute
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