Tetramethylammonium Difluoro(oxalato)borate as Novel Electrolyte for Electric Double-Layer Capacitors
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概要
- 論文の詳細を見る
The use of an asymmetric borate anion, difluoro(oxalato)borate (DFOB−), improves the solubility of the tetramethylammonium salt in propylene carbonate (PC) and the capacitances of electric double-layer capacitors (EDLCs). Electric conductivity of the PC solution containing tetramethylammonium difluoro(oxalato)borate (TMADFOB) was slightly lower than that obtained for tetraethylammonium tetrafluoroborate (TEABF4), but higher than those obtained for tetramethylammonium bis(oxalato)borate (TMABOB) and tetraethylammonium bis(oxalato)borate (TEABOB). The gravimetric capacitances of measurement cells increased with decreasing the ion sizes of the electrolytes. The PC solution containing TMADFOB afforded the highest gravimetric capacitance.
- 公益社団法人 電気化学会の論文
著者
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Uno Hiroyuki
Department Of Communications Engineering School Of Engineering Tokai University
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Nanbu Noritoshi
Department Of Applied Chemistry Faculty Of Engineering Tokyo Institute Of Polytechnics
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Suzuki Keita
Department Of Applied Chemistry Nagoya Institute Of Technology
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Sasaki Yukio
Department Of Applied Chemistry Faculty Of Engineering Tokyo Institute Of Polytechnics
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Ebina Takahito
Department Of Nanochemistry Faculty Of Engineering Tokyo Polytechnic University
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UNO Hiroyuki
Department of Nanochemistry, Faculty of Engineering, Tokyo Polytechnic University
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