モノフッ素化鎖状カーボネートの物性および電解液特性に及ぼす構造異性体の効果
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概要
- 論文の詳細を見る
Methyl propyl carbonate (MPC) shows a liquid temperature range that is wider than that of diethyl carbonate (DEC). Monofluorinated organic solvents exert the strong polar effect on the physical and the electrochemical properties. 2-Fluoropropyl methyl carbonate (2FPMC) and ethyl 2-fluoroethyl carbonate (E2FEC) are isomeric with each other. The relative permittivity and viscosity of 2FPMC were higher than those of E2FEC, MPC, and DEC. The ionic conductivity of 1 mol dm−3 LiPF6 solution in 2FPMC was lower than those in E2FEC, MPC, and DEC. The use of 2FPMC as a co-solvent greatly improved cycling efficiency of a lithium anode.
著者
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TAKEHARA Masahiro
Mitsubishi Chemical Group Science and Technology Research Center, Inc.
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Ue Makoto
Mitsubishi Chemical Corporation Tsukuba Research Center
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Sasaki Yukio
Department Of Applied Chemistry Faculty Of Engineering Tokyo Institute Of Polytechnics
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NAMBU Noritoshi
Department of Life Science and Sustainable Chemistry (Former name
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NACHI Tokuma
Department of Life Science and Sustainable Chemistry (Former name
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NACHI Tokuma
Department of Life Science and Sustainable Chemistry (Former name: Department of Nanochemistry), Faculty of Engineering, Tokyo Polytechnic University
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TAKEHARA Masahiro
Mitsubishi Chemical Group Science and Technology Research Center
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