The Fragmentation Mechanisms in CH3X Interpreted by Using the Molecular Orbital Method
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概要
- 論文の詳細を見る
The breakdown curves of various CH3X after charge exchange reactions were obtained using a double mass spectrometer of the perpendicular type, and it was found that the C-X bond was easy to dissociate in methylhalides(Group A)whereas it was not in methylamine, methanol and methylmercaptan(Group B). The difference of the C-X bond rupture between two groups was well explained on the basis of the eigenvectors calculated by the Extended Hiickel Molecular Orbital method. It is obvious that the fragmentation directly occurs at the bond at which the electron is ejected.
- 日本質量分析学会の論文
著者
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IKUTA SHIGERU
Department of Chemistry, Faculty of Science, Tohoku University
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SHIOKAWA TAKANOBU
Department of Cbemistry, Faculty of Science, Toboke University,
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YOSHIHARA KENJI
Department of Cbemistry, Faculty of Science, Toboke University,
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