Studies of Fragment Ion Distribution and Reaction by the Use of a Charge Spectrometer. VII. Fragmentation of Aliphatic Thiol Ions Produced by Charge Exchange with Positive Ions
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概要
- 論文の詳細を見る
Fragmentation of molecular ions of methanethiol, ethanethiol, two kinds of propanethiols, and four kinds of butanethiols formed by charge exchange with positive ions has been studied using a tandem mass spectrometer. The results are compared with those of the corresponding alcohols obtained by Lindholm and coworkers, and similarities and differences between both series of ions are pointed out. The effect of the structure of the molecule on fragmentation is discussed. The fragment ions derived from primary scission are predicted on the basis of the EHMO calculation.
- 公益社団法人 日本化学会の論文
著者
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IKUTA SHIGERU
Department of Chemistry, Faculty of Science, Tohoku University
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SHIOKAWA TAKANOBU
Department of Cbemistry, Faculty of Science, Toboke University,
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YOSHIHARA KENJI
Department of Cbemistry, Faculty of Science, Toboke University,
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Kobayashi Masanao
Department of Chemistry, Faculty of Science, Tohoku University
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