Thermal decomposition of graphite fluoride. I. Decomposition products of graphite fluoride, (CF)n in a vacuum.
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概要
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The mechanism of thermal decomposition of graphite fluoride, (CF)<I><SUB>n</SUB></I> in a vacuum was studied by means of chemical and gas analyses, and the measurement of crystallinity. The crystallinity of (CF)<I><SUB>n</SUB></I> was slightly improved in the step of initial decomposition. The fluorine/carbon atomic ratio of initial gaseous product evolved by decomposition was about 2. The product is CF<SUB>2</SUB> or C<SUB>2</SUB>F<SUB>4</SUB>, and then it gives several compounds by secondary reaction. Every second layers of (CF)<I><SUB>n</SUB></I> are decomposed, and the evolved molecules or radicals abstract fluorine atoms which are bonded to the neighboring two layers.
- 公益社団法人 日本化学会の論文
著者
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Koyama Satoshi
Department Of Cardiovascular Medicine Asahikawa Medical College
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Imoto Hiroki
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Watanabe Nobuatsu
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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