Some properties of fluorine-adsorbed active carbon.
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概要
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Properties of fluorine-adsorbed active carbon (FAAC), expected to be a new fluorinating agent, were investigated by means of TG, X-ray diffraction, and ESCA. The fluorine in FAAC was desorbed by heat treatment in a vacuum at temperatures higher than 200 °C. The X-ray diffraction and ESCA measurements suggest that fluorine is inserted between the carbon layer planes of the active carbon, and combines with carbon atoms weakly in comparison with the C–F covalent bond. The reactivity of FAAC against several organic compounds was studied. 1-Butanol, 1-butanethiol, and cyclohexylamine were oxidized. Butyryl chloride was fluorinated to give butyryl fluoride.
- 公益社団法人 日本化学会の論文
著者
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Ueno Kazuo
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Watanabe Nobuatsu
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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