Preparation of graphite intercalation compounds of thiazyl salts.
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概要
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Thiazyl salts prepared from S<SUB>3</SUB>N<SUB>3</SUB>Cl<SUB>3</SUB> and MCl<SUB>3</SUB>(M=Sb, Fe, Al) were intercalated into flaky or powdery natural graphite in CCl<SUB>4</SUB> or SOCl<SUB>2</SUB>. Intercalation compounds prepared are C<SUB>24</SUB>S<SUB>4</SUB>N<SUB>4</SUB>·2SbCl<SUB>5</SUB>[2nd stage, <I>I</I><SUB>c</SUB>(repeat distance)=12.81±0.02 Å], C<SUB>9.5</SUB>·0.2(S<SUB>3</SUB>N<SUB>3</SUB>Cl<SUB>3</SUB>·FeCl<SUB>2</SUB>)·0.8(SOCl<SUB>2</SUB>·FeCl<SUB>2</SUB>) [2nd stage, <I>I</I><SUB>c</SUB>=12.77±0.03 Å], C<SUB>11</SUB>S<SUB>3</SUB>N<SUB>3</SUB>Cl<SUB>3</SUB>· 2.4FeCl<SUB>2</SUB> [a mixture of 1st and higher stage compounds, <I>I</I><SUB>c</SUB>=9.17±0.05 Å] and C<SUB>24</SUB>·0.4(S<SUB>3</SUB>N<SUB>3</SUB>Cl<SUB>3</SUB>·2AlCl<SUB>2</SUB>)·0.6(SOCl<SUB>2</SUB>·2AlCl<SUB>2</SUB>) [a mixture of 2nd and 3rd stage compounds, <I>I</I><SUB>c</SUB>=12.89±0.03 Å, 16.23±0.03 Å]. Electrical conductivity of pyrolytic carbon–S<SUB>4</SUB>N<SUB>4</SUB>·2SbCl<SUB>5</SUB> [3rd stage] is higher than that of original pyrolytic carbon by one order.
- 公益社団法人 日本化学会の論文
著者
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Kawaguchi Masayuki
Department Of Chemistry And Biotechnology Graduate School Of Engineering The University Of Tokyo
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Watanabe Nobuatsu
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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Nakajima Tsuyoshi
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan
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Kawaguchi Masayuki
Department of Industrial Chemistry, Faculty of Engineering, Kyoto University
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