Isomerization of cyclohexene oxide over solid acids and bases.
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概要
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The reaction of cyclohexene oxide over solid acids and bases at 108 °C gave five main products, 1,3-cyclohexadiene (<B>1</B>), cyclohexanone (<B>2</B>), cyclohexanol (<B>3</B>), 2-cyclohexen-1-one (<B>4</B>), and 2-cyclohexen-1-ol (<B>5</B>). SiO<SUB>2</SUB>–TiO<SUB>2</SUB> and SiO<SUB>2</SUB>–TiO<SUB>2</SUB>–MgO were highly active for the isomerization, giving a large amount of <B>1</B>. TiO<SUB>2</SUB>–ZrO<SUB>2</SUB> mainly showed selectivity for the formation of <B>5</B>, and other catalysts formed both <B>2</B> and <B>5</B>. Of the alumina prepared in four different ways, two were highly active, giving <B>5</B> predominantly. The results were discussed in comparison with those for an oxide containing a methyl group on the oxide ring, 1-methylcyclohexene oxide. By the experiment using the deuterated epoxide, 1,2-epoxycyclohexane-3,3,6,6-<I>d</I><SUB>4</SUB>, isotope effects for the formation of <B>2</B>, <B>3</B>, <B>4</B>, and <B>5</B> over Al<SUB>2</SUB>O<SUB>3</SUB>'s, SiO<SUB>2</SUB>–TiO<SUB>2</SUB> and solid H<SUB>3</SUB>PO<SUB>4</SUB> were observed. It has been concluded that the epoxide is adsorbed on both acidic and basic sites, and that allyl alcohol is formed when both the opening of the epoxide ring and the hydrogen abstraction take place simultaneously, while ketone is formed when the former precedes the latter.
- 公益社団法人 日本化学会の論文
著者
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Tanabe Kozo
Department of Chemistry, Faculty of Science, Hokkaido University
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Arata Kazushi
Hokkaido University of Education
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