The Dehydration and Dehydrogenation of Ethanol Catalyzed by TiO<SUB>2</SUB>–ZrO<SUB>2</SUB>
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Ethanol was converted into ether, ethylene, and butadiene over TiO<SUB>2</SUB>–ZrO<SUB>2</SUB> with various contents of ZrO<SUB>2</SUB>in a flow system. Maximum acidity and activity were obtained at 50% ZrO<SUB>2</SUB>. The butadiene formation was explained by both dehydration and dehydrogenation reactions on acidic and basic sites, implying that TiO<SUB>2</SUB>–ZrO<SUB>2</SUB> is an acid-base bifunctional catalyst.
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- The Dehydration and Dehydrogenation of Ethanol Catalyzed by TiO2–ZrO2