Comparison of Lewis acids as catalyst for the alkylation of benzene with s-butyl chloride.
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概要
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The Friedel-Crafts alkylation of benzene with <I>s</I>-butyl chloride has been carried out in the presence of various Lewis acid catalysts. The relative order of catalyst activity is: AlBr<SUB>3</SUB>, AlCl<SUB>3</SUB>, MoCl<SUB>5</SUB>, SbCl<SUB>5</SUB>>TaCl<SUB>5</SUB>>NbCl<SUB>5</SUB>>FeCl<SUB>3</SUB>>ZrCl<SUB>4</SUB>>TiCl<SUB>4</SUB>>>WCl<SUB>6</SUB>. The effect of addition of nitromethane on alkylation has been investigated.
- 公益社団法人 日本化学会の論文
著者
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Nakajima Tadashi
Department Of Applied Biology Faculty Of Textile Science And Technology Shinshu University
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Suga Sohei
Department of Industrial Chemistry, Faculty of Technology, Kanazawa University
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Segi Masahito
Department of Industrial Chemistry, Faculty of Technology, Kanazawa University
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- Comparison of Lewis acids as catalyst for the alkylation of benzene with s-butyl chloride.