Mechanism of base catalyzed oxidation of 2-(1-hydroxyalkyl)-thiazolium ion with 3-methyllumiflavin.
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概要
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The oxidation of 2-(α-hydroxybenzyl)- and 2-(1-hydroxyethyl)thiazolium ions with 3-methyllumiflavin was studied kinetically in an aqueous buffer solution. The results indicate that the rate-determining step is carbanion formation followed by rapid oxidation. The carbanion formation was subjected to general base catalysis.
- 公益社団法人 日本化学会の論文
著者
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Hoshino Yutaka
Department Of Bioactive Molecules National Institute Of Infectious Diseases
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Yano Yumihiko
Department Of Chemistry Faculty Of Engineering Gunma University
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Tagaki Waichiro
Department of Applied Chemistry, Faculty of Engineering Osaka City University
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Tamura Yoshiharu
Department of Chemistry, Faculty of Engineering, Gunma University
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Hoshino Yutaka
Department of Chemistry, Faculty of Engineering, Gunma University
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