Mechanism of the reaction of (arylthio)trimethylgermanes with 1-aryl-1-bromoethanes. Kinetic and stereochemical studies.

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概要

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• Kinetic and stereochemical studies have been conducted on the reaction of (arylthio)trimethylgermanes with 1-aryl-1-bromoethanes. The reaction has been found to obey a first-order kinetic equation. The rates of the reaction of the substituted arylethanes were well-correlated with σ<SUP>+</SUP> constants. Optically active 1-bromo-1-phenylethane gave racemic phenyl 1-phenylethyl sulfide by the reaction with trimethyl(phenylthio)germane. An S<SUB>N</SUB>1 ionization of 1-aryl-1-bromoethanes has been suggested as the reaction mechanism.

• 公益社団法人 日本化学会の論文

著者

• Kozuka Seizi

  Department of Applied Chemistry, Faculty of Engineering, Osaka City University

• Tamura Shoji

  Department of Applied Chemistry, Faculty of Engineering, Osaka City University

• Tagaki Waichiro

  Department of Applied Chemistry, Faculty of Engineering Osaka City University

• Nitta Takemi

  Department of Applied Chemistry, Faculty of Engineering, Osaka City University

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