Resonance Raman spectra of intermolecular vibrations of Wuerster's cation dimers.
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概要
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The resonance Raman spectra of some Würster's cation dimers were measured in alcohol solution at 201 K and in glassy matrix at 77 K. The spectra of the dimer of <I>p</I>-phenylenediamine cation showed the resonance enhancement of the Raman line assigned to the intermolecular stretching vibration and supported the D<SUB>2h</SUB> symmetry for the dimer. However, for the dimer of 2,3,5,6-tetramethyl-<I>p</I>-phenylenediamine cation and <I>N</I>,<I>N</I>-dimethyl-<I>p</I>-phenylenediamine cation, it was supposed that D<SUB>2h</SUB> symmetry was broken down in alcohol solution and in glassy matrix, because the dimers had two Raman lines in the region of the intermolecular vibration.
- 公益社団法人 日本化学会の論文
著者
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Maeda Shiro
Research Laboratory Of Resources Utilization Tokyo Institute Of Technology
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Yokoyama Kenji
Research Center For Advanced Bionics National Institute Of Advanced Industrial Science And Technolog
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Tajima Yoshitaka
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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Tahara Masao
Research Laboratory of Resources Utilization, Tokyo Institute of Technology
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