Carbon-13 chemical shifts of polychlorobicyclo(2.2.1)heptene derivatives.
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概要
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The <SUP>13</SUP>C chemical shifts of 5-substituted polychlorobicyclo[2.2.1]heptene derivatives were determined. The chlorine, 5-<I>endo</I> and 5-<I>exo</I> substituent effects on the chemical shifts were discussed. The differences in the C<SUB>3</SUB>and C<SUB>7</SUB> chemical shifts are shown to be helpful for the identification of the <I>endo</I> and <I>exo</I> isomers. A possible operation of the interaction of pi electrons with a carbon-chlorine dipole is also discussed.
- 公益社団法人 日本化学会の論文
著者
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Sera Akira
Department Of Chemistry Faculty Of Science Kobe University
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Seguchi Kazuyoshi
Faculth Of Human Environmental Sciences Mukogawa Women's University
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Nakamura Michiko
Department of Chemistry, Faculty of Science, Kobe University
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Seguchi Kazuyoshi
Faculty of Home Economics, Mukogawa Women's University
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Takagi Kazuhiro
Department of Chemistry, Faculty of Science, Kobe University
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