13C and 19F chemical shifts induced by C-H...base hydrogen bonding. Particular polarizations of C-halogen and C=C bonds.
スポンサーリンク
概要
- 論文の詳細を見る
The <SUP>13</SUP>C and <SUP>19</SUP>F chemical shifts induced by C–H···Base hydrogen bonding were measured for dichlorofluoromethane, chloroform, pentachloroethane, and trichloroethylene. These chemical shifts were shown to be linear using the β scale of hydrogen-bond acceptor basicities proposed by Kamlet and Taft. The analysis of the linear solvation energy relationships reveals that the particular polarizations of the C–halogen and C=C bonds play an important role in the C–H···Base hydrogen-bond formation.
- 公益社団法人 日本化学会の論文
著者
-
Sera Akira
Department Of Chemistry Faculty Of Science Kobe University
-
Nakamura Michiko
Department of Chemistry, Faculty of Science, Kobe University
-
Ueji Shinichi
Department of Chemistry, College of General Education, Kobe University
-
Kitadani Masayuki
Department of Chemistry, College of General Education, Kobe University
関連論文
- Photo-Induced Reactions of Oxime O-Ethers Derived from 3-Acyl-1, 2-dihydrocinnoline- 1, 2-dicarboximides
- Novel Photo-Rearrangement of Oxime Methyl Ethers of 3-Acyl-1, 2dihydrocinnoline-N-phenyl-1, 2-dicarboximides
- NMR Study of Pressure Effect on the Hindered Rotation in cis-1, 12-Disubstituted[12]paracyclophanes
- ^1H NMR Study of the Reaction of Iron(III)Porphyrins with NaBH_4 in the Presence of Alkenes. Formation of Organoiron(III) Porphyrins
- Abnormality of circadian rhythm accompanied by an increase in frontal cortex serotonin in animal model of autism
- Advanced renal pelvic carcinoma associated with dermatomyositis
- Seizures and psychiatric symptoms of epileptics with frontally localized foci. II. The localization of the EEG abnormalities and psychiatric symptoms
- 13C and 19F chemical shifts induced by C-H...base hydrogen bonding. Particular polarizations of C-halogen and C=C bonds.
- Positive Associations between Dopamine D4 Receptor Polymorphism and Schizophrenia. A Study on Two Schizophrenic Groups with Genetic Loading and Unloading.:A Study on Two Schizophrenic Groups with Genetic Loading and Unloading
- Carbon-13 chemical shifts of polychlorobicyclo(2.2.1)heptene derivatives.
- Addition reaction of 1,4-dibromo-2,5-piperazinedione with 3,4-dihydro-2H-pyran.
- Photo-induced alkoxybromination of olefins by N,N'-dibromo-2,5-piperazinedione.
- Electrode kinetics of viologen polymers attached on graphite surfaces.
- The Effect of Milk and Skim Milk Intake on Serum Lipids and Apoproteins in Postmenopausal Females.
- Formation of 2-substituted 1,3-diphenylindenes by an N-bromosuccinimide prompted dehydrocyclization of 2-substituted 1,3,3-triphenyl-1-propenes.
- Titanium(III) Chloride Mediated Reduction of 1-Nitro-2-phenylethenes.
- Effect of Pressure on the Rate of Solvolysis. Formolysis of 1-(p-Substituted benzyl)ethyl Tosylates
- A Base-induced Elimination Reaction of Phenylsulfonylacetates. II. Effects of the Base and the Solvent on the Stereochemistry of Elimination