Electrochemical fixation of molecular nitrogen on p-type gallium phosphide photocathode.
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概要
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Electrochemical fixation of molecular nitrogen to ammonia and hydrazine at p-type GaP photocathodes was studied in nonaqueous electrolytes containing either one of titanium tetraisopropoxide, titanium trichloride, vanadium trichloride, or chromium trichloride and a trace amount of water. Positive evidences for the nitrogen fixation were obtained in these electrolytes, but the current efficiency was quite low, and usually less than 1%. It is suggested from the present study that there are a variety of choices of electrolyte systems for the nitrogen fixation.
- 公益社団法人 日本化学会の論文
著者
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TAMURA Hideo
Department of Applied Physics Faculty of Engineering Nagoya University
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Yoneyama Hiroshi
Department of Applied Chemisrty, Faculty of Engineering, Osaka University
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Koizumi Masashi
Department of Applied Chemistry, Faculty of Engineering, Osaka University
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