Heterogeneous reactions of nitrogen monoxide on titanium dioxide photocatalysts in solutions.

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概要

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• Heterogeneous reactions of nitrogen monoxide on illuminated TiO<SUB>2</SUB> catalysts in 1 mol dm<SUP>−3</SUP> HClO<SUB>4</SUB> were studied by electrochemical analysis. Nitrogen monoxide was reduced to ammonia and hydrazine. The main reaction was found to be a chemical reaction of hydroxylamine as a reaction intermediate with nitrogen monoxide to give molecular nitrogen. Nitrate was detected as an oxidation product formed by the counterpart reaction of the reduction of nitrogen monoxide.

• 公益社団法人 日本化学会の論文

著者

• TAMURA Hideo

  Department of Applied Physics Faculty of Engineering Nagoya University

• Yoneyama Hiroshi

  Department of Applied Chemisrty, Faculty of Engineering, Osaka University

• Shiota Hisashi

  Department of Applied Chemistry, Faculty of Engineering, Osaka University

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