Redox Reactions on the Lithiated Nickel Oxide Electrode
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概要
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The redox reactions of the Ce<SUP>3+</SUP>/Ce<SUP>4+</SUP>, Fe<SUP>2+</SUP>/Fe<SUP>3+</SUP> and Fe(CN)<SUB>6</SUB><SUP>4−</SUP>/Fe(CN)<SUB>6</SUB><SUP>3−</SUP> systems on lithiated nickel oxide electrodes in a H<SUB>2</SUB>SO<SUB>4</SUB> medium were studied. For the Fe<SUP>2+</SUP>/Fe<SUP>3+</SUP> and Fe(CN)<SUB>6</SUB><SUP>4−</SUP>/Fe(CN)<SUB>6</SUB><SUP>3−</SUP> systems, the reactions were controlled by an activation process when the electrode was polarized anodically, while the current tended to saturation as the current was increased in the cathodic direction. The apparent exchange current densities of these systems were distinctly dependent on the resistivity of the electrode. These phenomena were discussed qualitatively from a consideration of the energy states of the charge carriers in the electrode and redox systems, and it was concluded that all the reactions had proceeded through only hole transfer.
- 公益社団法人 日本化学会の論文
著者
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TAMURA Hideo
Department of Applied Physics Faculty of Engineering Nagoya University
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Yoneyama Hiroshi
Department of Chemical Technology, Faculty of Engineering, Osaka University
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Yoneyama Hiroshi
Department of Applied Chemisrty, Faculty of Engineering, Osaka University
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