Application of the water-gas shift reaction. III. Reduction of oxidized nitrogen compounds with CO and H2O catalyzed by (Ru(cod)py4)(BPh4)2.

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概要

• 論文の詳細を見る

• The ruthenium(II) complex, [Ru(cod)py<SUB>4</SUB>](BPh<SUB>4</SUB>)<SUB>2</SUB> (cod=1,5-cyclooctadiene, py=pyridine) has been shown to catalyze the reduction of oxidized nitrogen compounds with CO and H<SUB>2</SUB>O. In this reaction, primary, secondary, and tertiary nitroalkanes are converted into amides, ketones, and amines, respectively. Nitrosobenzene and picoline <I>N</I>-oxides are also reduciable to amines in good yields.

• 公益社団法人 日本化学会の論文

著者

• Okano Tamon

  Department Of Materials Science Faculty Of Engineering

• Fujiwara Kensuke

  Department Of Cardiology New Tokyo Hospital

• Kiji Jitsuo

  Department of Chemistry Faculty of Science Osaka University

• Konishi Hisatoshi

  Department of Environmental Chemistry & Technology, Tottori University

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