The preparation and catalytic properties of the silica-supported rhodium complex.

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概要

• 論文の詳細を見る

• The RhH<SUB>2</SUB>(O<SUB>2</SUB>COH)[P(<I>i</I>-Pr)<SUB>3</SUB>]<SUB>2</SUB> complex is attached to the phosphinated silica prepared from a new linking agent, Ph<SUB>2</SUB>PCH<SUB>2</SUB>CH<SUB>2</SUB>CH<SUB>2</SUB>Si(OCH<SUB>3</SUB>)<SUB>3</SUB>. The supported complex is an active catalyst for the hydrogenation of methyl cinnamate with CO and H<SUB>2</SUB>O, and it can be used repeatedly with little loss of activity, whereas the polystyrene-supported one is not recoverable because of the insufficient complexation of the rhodium.

• 公益社団法人 日本化学会の論文

著者

• Kobayashi Teruyuki

  Department Of Chemistry Faculty Of Science Yamagata University

• Okano Tamon

  Department Of Materials Science Faculty Of Engineering

• Kiji Jitsuo

  Department of Chemistry Faculty of Science Osaka University

• Konishi Hisatoshi

  Department of Environmental Chemistry & Technology, Tottori University

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