Simple synthesis and chemicophysical properties of polyoxa(n)ferrocenophanes and its alkali metal complexes.
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概要
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Polyoxaferrocenophanes were synthesized by a one-pot reaction of 1,1′-diacetoxyferrocene with dichloride. Crystalline 1 : 1 complexes of <B>3a</B> with LiSCN, NaSCN, and KSCN were isolated. The <SUP>1</SUP>H-NMR and Mössbauer spectra of these complexes suggest the possibility of a certain interaction between the iron atom of the ferrocene nuclei and complexed cation. The new type of ferrocenophane <B>3a</B> extracts a thallium ion most effectively, the extractability of several metal ions being in this order; Tl<SUP>+</SUP>>Rb<SUP>+</SUP>>K<SUP>+</SUP>>Cs<SUP>+</SUP>>Na<SUP>+</SUP>.
- 公益社団法人 日本化学会の論文
著者
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Akabori Sadatoshi
Department Of Chemistry Faculty Of Science Toho University
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Sato Masaru
Chemical Analysis Center Saitama University
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Ebine Seiji
Department of Chemistry, Faculty of Science and Engineering, Saitama University
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Habata Yoichi
Department of Chemistry, Faculty of Science, Toho University
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Akabori Sadatoshi
Department of Chemistry, Toho University
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Sakamoto Yhoko
Department of Chemistry, Toho University
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Habata Yoichi
Department of Chemistry, Toho University
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