The preparation and some properties of 1,4,7-trithia(7)- and 1,5,9-trithia(9)ferrocenophanes and their copper(I), silver(I), mercury(II), and palladium(II) complexes.
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概要
- 論文の詳細を見る
1,5,9-Trithia[9]ferrocenophane was prepared by the reaction of 1,1′-bis(3-chloropropylthio)ferrocene with sodium sulfide. The complexes of 1,5,9-trithia[9]ferrocenophane, along with 1,4,7-trithia[7]ferrocenophane, with copper(I), silver(I), mercury(II), and palladium(II) salts were prepared. Some interaction between the iron atom and the metal atoms coordinated to the thia-crown moiety was suggested from their spectral data in the solution for the complexes of 1,4,7-trithia[7]ferrocenophane with mercury(II) and palladium(II) salts and the complex of 1,5,9-trithia[9]ferrocenophane with silver(I) tetrafluoroborate.
- 公益社団法人 日本化学会の論文
著者
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Akabori Sadatoshi
Department Of Chemistry Faculty Of Science Toho University
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Sato Masaru
Chemical Analysis Center Saitama University
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Suzuki Kaoru
Chemical Analysis Center, Saitama University
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