Preparation and spectral behavior of polyoxadithia(n)ferrocenophanes and their silver(I) nitrate complexes.
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概要
- 論文の詳細を見る
Polyoxadithia[<I>n</I>]ferrocenophanes and polyoxatetrathia[<I>n</I>.<I>n</I>]ferrocenophanes were prepared by treatment of 1,1′-ferrocenedithiol with α,ω-dibromo polyethers. The ferrocenophanes formed efficiently a complex with a silver ion, but not with alkali and alkali-earth metal ions. The spectral data of the silver ion-complexed ferrocenophanes suggested the presence of a partial electron-transfer interaction between the iron atom and the complexed silver ion.
- 公益社団法人 日本化学会の論文
著者
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Akabori Sadatoshi
Department Of Chemistry Faculty Of Science Toho University
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Sato Masaru
Chemical Analysis Center Saitama University
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Ebine Seiji
Department of Chemistry, Faculty of Science and Engineering, Saitama University
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Kubo Masao
Chemical Analysis Center, Saitama University
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