Reaction of allene with water catalyzed by palladium(0) in the presence of carbon dioxide.
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概要
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A novel reaction involving allene and water took place using palladium(0)–triphenylphosphine as a catalyst in the presence of carbon dioxide to yield 3-methyl-2-methylene-3-buten-1-ol, selectively. A related reaction of allene with methanol or ethanol was found to occur without carbon dioxide.
- 公益社団法人 日本化学会の論文
著者
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Inoue Yoshio
Department Of Biomolecular Engineering Graduate School Of Engineering Tohoku University
-
Hashimoto Harukichi
Department of Applied Chemistry, Faculty of Engineering, Tohoko University
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Ohtsuka Yukihiro
Department of Applied Chemistry, Faculty of Engineering, Tohoko University
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