1H NMR study of conformation of formyl-L-phenylalanyl-6-deoxy-6-amino-cyclomaltoheptaose that has excellent ability of chiral recognition.
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概要
- 論文の詳細を見る
<I>N</I>-(<I>N</I>-Formyl-L-phenylalanyl)-6-deoxy-6-aminocyclomaltoheptaose (f-L-Phe-β-CD) is one of CD derivatives with excellent ability of chiral recognition. In order to make clear the mechanism of chiral recognition, the conformation of free f-L-Phe-β-CD has been studied by using <SUP>1</SUP>H and <SUP>13</SUP>C nuclear magnetic resonance (NMR) spectroscopy. From the measurement of <SUP>1</SUP>H homonuclear Overhauser enhancement on the rotating frame, it is concluded that f-L-Phe- residue of the f-L-Phe-β-CD is inserted into its cavity from the upside of primary hydroxyl groups of the macrocyclic ring. Analysis of <SUP>1</SUP>H and <SUP>13</SUP>C spectra of f-L-Phe-β-CD and model compounds of f-L-Phe- residue also support this conclusion. The macrocyclic ring is found to be distorted.
- 公益社団法人 日本化学会の論文
著者
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Yamamoto Yasuhiko
Department Of Biochemistry And Molecular Vascular Biology Kanazawa University Graduate School Of Med
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Hattori Kenjiro
Department Of Applied Chemistry Faculty Of Engineering Tokyo Institute Of Polytechnics
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Chujo Riichiro
Department Of Material Engineering The Nishi - Tokyo - University
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Takahashi Keiko
Department Of Applied Chemistry Faculty Of Engineering Tokyo Institute Of Polytechnics
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Inoue Yoshio
Department Of Biomolecular Engineering Graduate School Of Engineering Tohoku University
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Saka Wataru
Department of Biomolecular Engineering, Tokyo Institute of Technology
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Takahashi Keiko
Department of Industrial Chemistry, Tokyo Institute of Polytechnics
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