The reaction of N-aryl-C-ethoxycarbonylnitrilimine with olefins.
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概要
- 論文の詳細を見る
<I>C</I>-Ethoxycarbonylnitrilimines treated with monosubstituted olefins predominantly gave 5-substituted 3-ethoxycarbonyl-2-pyrazolines. From the analysis of the relative rate and regioselectivity of a variety of monosubstituted olefins for the cycloaddition, the nitrilimine is shown to have reactivity and regioselectivity similar to the throughly studied diphenylnitrilimine. The cycloaddition regioselectivity is discussed in terms of frontier orbital energies and coefficients.
- 公益社団法人 日本化学会の論文
著者
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Nishio Toshiyuki
Department Of Biological Chemistry College Of Bioresource Sciences Nihon University
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Teramura Kazuhiro
Department Of Pathology Wakakusa Dai-ichi Hospital
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Hayashi Yoshiyuki
Department Of Acoustic Design Kyusyu Institute Of Design
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Shimizu Tomio
Department of Dyeing, Faculty of Industrial Arts, Kyoto Technical University
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Nishio Toshiyuki
Department of Color Chemistry and Technology, Faculty of Industrial Arts, Kyoto Technical University
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