Synthesis of 2,6,8-trinitro-4H-cyclopenta(def)phenanthren-4-one as an electron acceptor.
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概要
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2,6,8-Trinitro-4<I>H</I>-cyclopenta[<I>def</I>]phenanthren-4-one (TNC) was synthesized by the nitration of the parent ketone. TNC formed charge-transfer complexes with polycyclic aromatic hydrocarbons (PAH). The property of TNC as an electron acceptor was compared with that of 2,4,7-trinitro-9<I>H</I>-fluoren-9-one (TNF). TNC was found to be a better complexing agent than TNF.
- 公益社団法人 日本化学会の論文
著者
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Minabe Masahiro
Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University
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Yoshida Masaaki
Department Of Applied Chemistry Faculty Of Engineering Utsunomiya University
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Kimura Okitoshi
Department of Industrial Chemistry, Faculty of Engineering, Utsunomiya University
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