Reaction of substituted benzaldehydes with sodium hydrogensulfide or sodium sulfide in liquid ammonia.

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概要

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• Reactions of substituted benzaldehydes with sodium hydrogensulfide in the presence of nitrobenzene, nitrosobenzene, or azobenzene in liquid ammonia produce the corresponding benzyl alcohols and benzamides. On the other hand, reaction of benzaldehyde with sodium sulfide produces benzyl alcohol and benzamide. A reaction mechanism has been proposed which involves benzaldehyde anion radical.

• 公益社団法人 日本化学会の論文

著者

• Takikawa Yuji

  Department Of Applied Chemistry And Molecular Science Faculty Engineering Iwate University

• Sato Ryu

  Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwate University

• Shimada Kazuaki

  Department Of Applied Chemistry And Molecular Science Faculty Of Engineering Iwata University

• Minami Tetsuo

  Department of Applied Chemistry, Faculty of Engineering, Iwate University

• Takizawa Saburo

  Department of Applied Chemistry, Faculty of Engineering, Iwate University

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