Moessbauer spectroscopic studies of the correlation between molecular structure and sign of quadrupole splitting in tris(.BETA.-diketonato)iron(III) complexes utilizing paramagnetic relaxation effects.

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概要

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• The change of the Mössbauer line shape with the paramagnetic relaxation time was studied in several tris(β-diketonato)iron(III) complexes to determine the sign of the quadrupole splitting. The correlation observed between the molecular structure and the sign of the quadrupole splitting demonstrates that the sign should depend on the bond angle (∠O–Fe–O) in iron(III) complexes.

• 公益社団法人 日本化学会の論文

著者

• Yamauchi Shigeru

  Department of Chemistry, Faculty of Science, The University of Tokyo

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• Moessbauer spectroscopic studies of the correlation between molecular structure and sign of quadrupole splitting in tris(.BETA.-diketonato)iron(III) complexes utilizing paramagnetic relaxation effects.

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