Crystal structure of 6-(6(e)-carbamoyltetrahydro-2(e)-pyranyl)-8-oxa-6-azabicyclo(3.2.1)octan-7-one.
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概要
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The structure of the dimerization product of bicyclic oxalactam, 8-oxa-6-azabicyclo[3.2.1] octan-7-one, was determined by the X-ray diffraction method. The final <I>R</I> value was 0.062 for 2009 reflections. The structure suggests that the cationic oligomerization of the bicyclic oxalactam proceeds through the C<SUP>5</SUP>–N<SUP>6</SUP> scission, differing from the cases of other common lactams.
- 公益社団法人 日本化学会の論文
著者
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Ashida Tamaichi
Department Of Biotechnology School Of Engineering Nagoya University
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Hashimoto Kazuhiko
Faculty Of Engineering Kougakuin University
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Yamane Takashi
Department Of Biotechnology And Biomaterial Chemistry Graduate School Of Engineering Nagoya Universi
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Sumitomo Hiroshi
Faculty of Agriculture, Nagoya University
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Nanayama Hiroto
Department of Applied Chemistry, Faculty of Engineering, Nagoya University
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Yamane Takashi
Department of Applied Chemistry and Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University
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Hashimoto Kazuhiko
Faculty of Agriculture, Nagoya University
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Ashida Tamaichi
Department of Applied Chemistry and Department of Synthetic Chemistry, Faculty of Engineering, Nagoya University
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