Direct evidence for the peroxo substitution of the oxo group in the oxotitanium(IV) porphyrin complex in the aqueous solution.
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概要
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Labeling experiments for IR and NMR spectra of oxo- and peroxotitanium(IV) complexes show that the oxo group of oxotitanium(IV) porphyrin is fully substituted by a peroxo group in the course of the reaction with hydrogen peroxide in the aqueous solution, i.e. the O–O bond of H<SUB>2</SUB>O<SUB>2</SUB> remains intact in the peroxo complex.
- 公益社団法人 日本化学会の論文
著者
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FUNAHASHI Shigenobu
Laboratory of Analytical Chemistry, Faculty of Science, Nagoya University
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Inamo Masahiko
Department Of Chemistry Aichi University Of Education
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Funahashi Shigenobu
Laboratory Of Analytical Chemistry Department Of Chemistry Faculty Of Science Nagoya University
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INAMO Masahiko
Department of Chemistry, Faculty of Education, Aichi University of Education
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Tanaka Motoharu
Laboratory of Analytical Chemistry Faculty of Science Nagoya University
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