Theoretical Study of Solvent-Exchange Reactions on Hexasolvated Divalent Cations in the First Transition Series : Model Calculation of a Hydrogen Cyanide Exchange

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概要

• 論文の詳細を見る
• Chemical Society of Japanの論文
• 2003-09-15

著者

• Wasada Hiroaki

  Faculty Of Regional Studies Gifu University

• FUNAHASHI Shigenobu

  Laboratory of Analytical Chemistry, Faculty of Science, Nagoya University

• Wasada Tsutsui

  Institute Of Natural Sciences Nagoya City University

• Funahashi Shigenobu

  Laboratory Of Analytical Chemistry Faculty Of Science Nagoya University

• Funahashi Shigenobu

  Laboratory Of Analytical Chemistry Department Of Chemistry Faculty Of Science Nagoya University

• Wasada-Tsutsui Yuko

  Institute of Natural Sciences, Nagoya City University

関連論文

• Crystal Structures of Trifluoromethanesulfonato Complexes of Nickel(II)and Palladium(II), [Ni(bpy)_2(CF_3SO_3)_2] and [Pd(triphosphine)(CF_3SO_3)](CF_3SO_3)・C_6H_6, and Characterization of the Coordination Ability of CF_3SO_3-
• Electronic Effect of Substituents on Cyclopalladation of the Solvated Palladium(II) Complexes with N-Benzyl Triamine [Pd(Sol){(4-XC_6H_4CH_2(NH(CH_2)_3NR(CH_2)_3NH_2}]^ (Sol=Solvent; R=Ph, H, and Me; X=H,Et, Me, MeO, Cl, and NO_2)
• The Structural Stability of Seven-Coordinate Divalent Cations in the First Transition Series Relevant to the Water-Exchange Reaction Mechanism
• Mechanistic Studies on Cyclopalladation of the Solvated Palladium(II) Complexes with N-Benzyl Triamine Ligands in Various Solvents. Crystal Structures of [Pd(Sol)(Bn_2Medptn)](BF_4)_2(Sol=Acetonitrile and N,N-Dimethylformamide ; Bn_2Medptn=N,N'-Dibenzyl-4
• The Stability of Seven-Coordinate Species of Earlier Members in the First Transition Series : Heptahydrated Ti(II), V(II), Cr(II), and Mn(II) Ions Relevant to Intermediate and Transition State in Water-Exchange Reaction
• Theoretical Study of Water-Exchange Reactions of Hexahydrated Divalent Cations in the First Transition Series: Relationship between Reaction Mechanism and Stability of Heptacoordinated Species
• Solvation Structure Determination of Nickel(II) Ion in Six Nitriles Using Extended X-Ray Absorption Fine Structure Spectroscopy
• Kinetics and Mechanism of Cyclopalladation for [Pd(S)(Bn_2Medptn)](BF_4)_2(S=Solvent, Bn_2Medptn=N, N''-Dibenzyl-N'-methyl-3, 3'-diaminodipropylamine)and Its Derivatives
• Crystal Structures and Acetonitrile Exchange of Palladium(II) Complexes with Bis(3-aminopropyl)amine and Diethylenetriamine. Effects of Ion-Pair Formation
• Dissociative Path Promoted by Ion Pair Formation for Acetonitrile Exchange Reaction of the Palladium(II) Complex with Diethylenetriamine
• Thiolato-Ligand Substitution Reaction with Halide Ions of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complexes with Tris(2-(diphenylphosphino)ethyl)phosphine. Electronic and Steric Effects on the Reaction Mechanism
• Spectrophotometric Analysis of 5-Coordinate Cobalt(II) Species for Ligand Substitution of Hexakis(acetonitrile)cobalt(II)with Bulky 1,1,3,3-Tetramethylurea in Noncoordinating Nitromethane
• Dynamic Study of Metal-Ion Incorporation into Porphyrins Based on the Dynamic Characterizatin of Metal Ions and on Sitting-Atop Complex Formation
• Solvation Structures and Solvent Exchange Reactions of Metal Ions in Various Coordinating Solvents
• Theoretical Study of Solvent-Exchange Reactions on Hexasolvated Divalent Cations in the First Transition Series : Model Calculation of a Hydrogen Cyanide Exchange
• VariablelTemperature and -Pressure Nitrogen-14 Magnetic Resonance Studies on Solvent Exchange of Nickel(II), Iron(II), and Manganese(I) Ions in Neat 1,3-Propanediamine and n-Propylamine
• Effects of the π and π^* Orbitals of the 5-Unsaturated Substituents on the π-Facial Selectivities in the Diels-Alder Reactions of Cyclopentadienes
• Kinetics and Mechanism for the Metalation Reaction of 5, 10, 15, 20-Tetrakis(pentafluorophenyl)porphyrin with Diaquabis(1, 1, 1, 5, 5, 5-hexafluoropentane-2, 4-dionato)nickel(II) in Supercritical Carbon Dioxide
• Characterization of σ and π Donation of Solvents by ^P NMR Chemical Shifts of Trigonal-Bipyramidal Palladium(II)Complexes with Tris(2-diphenylphosphinoethyl)phosphine
• Iodo-Ligand Substitution of [Pd(pp_3)I]^+ (pp_3 = Tris(2-diphenylphosphinoethyl)phosphine) by Trimethylphosphite. The First Proposition of the Associative Ligand-Substitution Mechanism of Trigonal-Bipyramidal Five-Coordinate Palladium(II) Complex
• Characterization and Equilibrium of Beryllium(II) Solvates [BeS_n(H_2O)_]^ (n=0-4, S=N, N-Dimethylformamide and 1, 1, 3, 3-Tetramethylurea) Studied by ^9Be NMR Spectroscopy
• Reevaluation of Donor Number Using Titration Calorimetry
• Metal complexes in acetic acid. I. Kinetics and mechanism of reactions of tetra-.MU.-acetato-dicopper(II) with lithium chloride and hydrogen chloride.
• Kinetics of the Ligand Substitution Reaction of the Copper(II)-4-(2-Pyridylazo)resorcinol Complex with (Ethylene glycol)-bis(2-aminoethyl ether)-N,N,N′,N′-tetraacetic Acid
• Kinetics of ligand substitution reaction of some aminopolyacetatonickel(II) complexes with reference to activation parameters.
• Kinetics of the Ligand Substitution Reaction of the Cobalt(II)-(Ethylene glycol)bis(2-aminoethyl ether)-N,N,N′,N′-tetraacetate Complex with 4-(2-Pyridylazo)resorcinol
• Solvent Bulkiness Effect on N,N-Dimethylformamide Exchange of the o-Phenylenediamine-N,N,N',N'-tetraacetatoferrate(III) Complex as Studied by a High-Pressure NMR Method.
• Kinetics and mechanism of complex formation of nickel(II) with 1-(2-pyridylazo)-2-naphthol in acetic acid.
• Kinetics of axial substitution of the iron(II) complex of 2,3,9,10-tetraphenyl-1,4,8,11-tetraaza-1,3,8,10-cyclotetradecatetraene in acetonitrile. Evidence for a dissociative-interchange mechanism.
• Kinetics and mechanism of copper(II), zinc(II), and cadmium(II) incorporation into 5,10,15,20-tetraphenylporphine and N-methyl-5,10,15,20-tetraphenylporphine in N,N-dimethylformamide.
• Kinetics and mechanism of cobalt(II) incorporation into meso-tetra(4-pyridyl)porphine in acetic acid.
• Direct evidence for the peroxo substitution of the oxo group in the oxotitanium(IV) porphyrin complex in the aqueous solution.
• Kinetics and Mechanism of Formation of Monothiocyanato and Mononitrilotriacetato Complexes of Iron(III)
• Kinetics and Mechanism of the Ligand Substitution Reaction of the Mercury(II)-4-(2-pyridylazo)resorcinol Complex with 1,2-Cyclohexanediamine-N,N,N′,N′-tetraacetic Acid
• Variable-temperature and variable-pressure nitrogen-14 NMR studies on the exchange reaction of different nitriles at the nickel(II) ion.

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