Ion/molecule reactions in gaseous acetone.
スポンサーリンク
概要
- 論文の詳細を見る
The ion/molecule reactions in acetone were investigated which were induced by the electron impact. It was found that the protonated acetone reacts with an acetone molecule to produce the protonated diacetone alcohol (4-hydroxy-4-methyl-2-pentanone) and the protonated mesityl oxide (4-methyl-3-penten-2-one) through the aldol condensation reaction. It was also found that the acetone molecule isomerizes from keto to enol form in the interaction with the chloride ion. The thermochemical data for the higher-order clustering reactions of the proton and chloride ion with acetone molecules were obtained.
- 公益社団法人 日本化学会の論文
著者
-
Hiraoka Kenzo
Faculty Of Engineering Yamanashi University
-
Shoda Takashi
Faculty Of Engineering Yamanashi University
-
Nakamura Shizuo
Ulvac Co.
-
Shoda Takashi
Faculty of Engineering, Yamanashi University
-
Takimoto Hajime
Faculty of Engineering, Yamanashi University
-
Morise Kazuya
Faculty of Engineering, Yamanashi University
関連論文
- Application of 10.6μm CO_2 Laser to the Electrospray and Ion Spray LC/MS Interface
- Segregation of As on GaAs(100) Surface during Abrasiorn Process Studied by X-Ray Photoelectron Spectroscopy and Auger Electron Spectroscopy
- Measurements of Molecular Densities in Low Pressure Discharge Plasmas Using Laser Raman Scattering
- Analysis of Polyethyleneterephthalate Film Surface Sputtered with Ar Neutral and Ar Jon Beams
- Operation of a CSL Gauge in Extremely High Vacuum
- Why Is Ethylene Missing in the Coma of the Comets Hyakutake and Hale-Bopp? (TMS特集号)
- Gas-Phase Ion-Molecule Reactions in Tetrahydrothiophene
- XHV System for Surface Analysis Using a New Getter to Reduce Hydrogen
- Submitting to International Symposium on Fusion Nuclear Technology
- Gas-Phase Solvation of O^+_2, O^+_4, and O^+_6 with Ar
- Electrochemical Reduction and Highly-Sensitive Analysis of Iodine in Electrospray Mass Spectrometry
- Formation of the [M+H]^+ and Abundant Fragment Ions of Methyl Stearate under Low Energy Electron Ionization Conditions
- Gas-Phase Polymerization Reactions Induced by the C_2H^+_m Ions (m=3-5) in Ethene
- Do the Electrospray Mass Spectra Reflect the Ion Concentrations in Sample Solution?
- Chemical evolution on the dust grains in the dark clouds: Experimental Approach
- Chemiluminescence from reactions of N2*(A3.SIGMA.u+) with solid organic compounds at 77 K.
- Ion/molecule reactions in gaseous acetone.
- Ion/molecule reactions in gaseous isopropyl alcohol.